Verified Solution • 2025–26 Session moderate

QPages 34-37: Q39: HC Verma: Concepts of Physics - Volume 2 Kinetic Theory of Gases Pages 34-37: Q39 Solution: Show that the internal energy of the air treated as an ideal…

Show that the internal energy of the air treated as an ideal gas) contained in a room remains constant as the temperature changes between day and night. Assume that the atmospheric pressure around remains constant and the air in the room maintains this pressure by communicating with the surrounding through the windows, doors, etc. Use R=8.314 J K−1 mol−1R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}

Step-by-Step Verified Solution

**Answer:** The internal energy of the air in the room remains constant. **Step-by-Step Explanation:** For an ideal gas, internal energy U=f2nRTU = \frac{f}{2}nRT where ff is degrees of freedom. From ideal gas law: nRT=PVnRT = PV. So U=f2PVU = \frac{f}{2}PV. The room communicates with the surroundings through windows/doors, so the pressure inside equals atmospheric pressure P0P_0 (constant). The volume VV of the room is fixed. Therefore:
U=f2P0V=constantU = \frac{f}{2}P_0 V = \text{constant}
Even though temperature changes between day and night, the number of moles nn changes (air enters/leaves), keeping PVPV and hence UU constant.

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