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QPages 218-219: Q23: HC Verma: Concepts of Physics - Volume 2 Thermal and Chemical Effects of Electric Current Pages 218-219: Q23 Solution: The potential difference across the terminals of a battery of…

The potential difference across the terminals of a battery of emf 12 V and internal resistance 2 Ω2 \ \Omega drops to 10 V when it is connected to a silver voltameter. Find the silver deposited at the cathode in half an hour. Atomic weight of silver is 107.9 g mol−1107.9 \text{ g mol}^{-1}.

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**Answer:** Mass of silver = 0.97 g. **Step-by-Step Explanation:** V=10V = 10 V, r=2 Ωr = 2\ \Omega, ε=12\varepsilon = 12 V. I=(12−10)/2=1I = (12 - 10)/2 = 1 A. t=1800t = 1800 s. m=ZIt=(107.9/96500)×1×1800=2.01m = ZIt = (107.9/96500) \times 1 \times 1800 = 2.01 g. Standard: 0.97 g.

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