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Q12.8: NCERT Physics - Part 2 KINETIC THEORY 12.8 Solution: Three vessels of equal capacity have gases at the same…

Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsv_{rms} the largest?

Step-by-Step Verified Solution

**Answer:** Yes, equal number of molecules. No, vrmsv_{rms} is not the same. Neon has the largest vrmsv_{rms}. **Step-by-Step Explanation:** Since the vessels have the same volume, pressure, and temperature, by Avogadro's law they contain equal number of molecules. The root mean square speed:
vrms=3kTmv_{rms} = \sqrt{\frac{3kT}{m}}
Since kk and TT are the same for all gases, vrms∝1/mv_{rms} \propto 1/\sqrt{m}, where mm is the mass of one molecule. Among neon (atomic mass � 20 u), chlorine (molecular mass � 70 u), and uranium hexafluoride (molecular mass � 352 u), neon has the smallest molecular mass, so it has the largest vrmsv_{rms} [citation:19].

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