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Q1.15: NCERT Physics - Part 1 UNITS AND MEASUREMENT 1.15 Solution: One mole of an ideal gas at standard temperature and pressure…

⚠️ Common Exam Traps & Conceptual Pitfalls

Students frequently mistake the given molecular size of 1 Å as the radius, failing to halve it to $0.5 imes 10^{-10}$ m before cubing. This oversight leads to an error factor of 8 in the atomic volume calculation, significantly skewing the final ratio.

One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1 �). Why is this ratio so large?

Step-by-Step Verified Solution

**Answer:** Ratio = 7.1×1047.1 \times 10^4. **Step-by-Step Explanation:** Molar volume = 22.4 L=2.24×10−2 m322.4 \text{ L} = 2.24 \times 10^{-2} \text{ m}^3. Molecular radius r=0.5 �=0.5×10−10 mr = 0.5 \text{ �} = 0.5 \times 10^{-10} \text{ m} (diameter = 1 �). Volume of one molecule = 43πr3=5.24×10−31 m3\frac{4}{3}\pi r^3 = 5.24 \times 10^{-31} \text{ m}^3. Volume of 1 mole of molecules = 6.022×1023×5.24×10−31=3.15×10−7 m36.022 \times 10^{23} \times 5.24 \times 10^{-31} = 3.15 \times 10^{-7} \text{ m}^3. Ratio = 2.24×10−23.15×10−7=7.1×104\frac{2.24 \times 10^{-2}}{3.15 \times 10^{-7}} = 7.1 \times 10^4. The ratio is large because gas molecules are very far apart compared to their size.

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