Verified Solution • 2025–26 Session moderate

QNEET-2024-Ch-94: NEET 2024 Chemistry - Class 11 NEET-2024-Ch-94 Solution: Identify the incorrect statement about \(PCl_5\). \(PCl_5\)…

Identify the incorrect statement about PCl5PCl_5. PCl5PCl_5 possesses two different Cl−P−ClCl-P-Cl bond angles All five P−ClP-Cl bonds are identical in length PCl5PCl_5 exhibits sp3dsp^3d hybridisation PCl5PCl_5 consists of five P−ClP-Cl (sigma) bonds

Multiple Choice Options

  • A PCl5\mathrm{PCl}_5 PCl 5 _ possesses two different Cl−P−Cl\mathrm{Cl}-\mathrm{P}-\mathrm{Cl} Cl _ P _ Cl bond angles
  • B All five P−Cl\mathrm{P}-\mathrm{Cl} P _ Cl bonds are identical in length
  • C PCl5\mathrm{PCl}_5 PCl 5 _ exhibits sp3ds p^3 d s p 3 d hybridisation
  • D PCl5\mathrm{PCl}_5 PCl 5 _ consists of five P−Cl\mathrm{P}-\mathrm{Cl} P _ Cl (sigma) bonds

Step-by-Step Verified Solution

It is s p 3 d hybridised with axial to equatorial angle of 90 _ and equatorial bond angles of 120 _ . It has five P _ Cl sigma bonds. Axial bonds are longer than equatorial bonds.

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