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QNEET-2024-Ch-41: NEET 2024 Chemistry - Class 12 NEET-2024-Ch-41 Solution: The Henry's law constant (\(K_H\)) values of three gases (A B…
The Henry's law constant () values of three gases (A B C) in water are 145 and 35 kbar respectively. The solubility of these gases in water follow the order: B > A > C B > C > A A > C > B A > B > C
Multiple Choice Options
- A B > A > C
- B B > C > A
- C A > C > B
- D A > B > C
Step-by-Step Verified Solution
According to Henry's law, the solubility of a gas in a liquid under constant temperature is directly proportional to the partial pressure of the gas above the liquid but is inversely proportional to the Henry's law constant ( K H ) for the gas. Henry's law can be expressed as:
c = P K H
where c is the concentration (or solubility) of the gas in the liquid, P is the partial pressure of the gas, and K H is Henry's law constant.
From the equation, it is clear that the solubility of the gas is inversely related to K H ; if K H increases, the solubility decreases, and vice versa.
In the given problem, you have the K H values of the gases A, B, and C as follows:
A: 145 kbar
B: 2 _ 10 _ 5 kbar
C: 35 kbar
Comparing the K H values:
Gas B has the lowest K H and hence the highest solubility.
Gas A, with the highest K H among the three, will have the lowest solubility.
Gas C has a K H value less than A but greater than B, so its solubility will be lower than B but higher than A.
Therefore, the order of solubility of the gases in water from the highest to the lowest is:
B > C > A
Thus, the correct option is:
Option B: B > C > A