Verified Solution • 2025–26 Session
moderate
QNEET-2024-Ch-120: NEET 2024 Chemistry - Class 11 NEET-2024-Ch-120 Solution: For the following reaction at 300 K \(A_2(g) + 3B_2(g)…
For the following reaction at 300 K the enthalpy change is +15 kJ then the internal energy change is: 19988.4 J 200 J 1999 J 1.9988 kJ
Multiple Choice Options
- A 19988.4 J
- B 200 J
- C 1999 J
- D 1.9988 kJ
Step-by-Step Verified Solution
To determine the internal energy change (_U) for the reaction at 300 K , we will use the relationship between enthalpy change (_H) and internal energy change:
_ H = _ U + _ n R T
where _ H is the enthalpy change, _ U is the internal energy change, _ n is the change in moles of gas, R is the universal gas constant, and T is the temperature.
Given:
_ H = + 15 kJ = 15000 J
T = 300 K
R = 8.314 J mol _ 1 K _ 1
_ n = moles of products _ moles of reactants
From the balanced chemical equation:
A 2 ( g ) + 3 B 2 ( g ) _ 2 AB 3 ( g )
Moles of reactants = 1 (for A 2 ) + 3 (for B 2 ) = 4 moles
Moles of products = 2 (for AB 3 )
Therefore, _ n = 2 (products) - 4 (reactants) = -2
Now, substituting these values into the equation:
_ H = _ U + _ n R T
15000 = _ U + ( _ 2 ) ( 8.314 ) ( 300 )
Simplify the equation:
15000 = _ U _ 4988.4
Therefore:
_ U = 15000 + 4988.4 = 19988.4 J
Hence, the internal energy change is:
Option A: 19988.4 J