Verified Solution • 2025–26 Session
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QNEET-2024-Ch-109: NEET 2024 Chemistry - Class 12 NEET-2024-Ch-109 Solution: The standard cell potential of the following cell \(Zn
The standard cell potential of the following cell is 0.32 V. Calculate the standard Gibbs energy change for the reaction: (Given: ) -61.75 kJ +5.006 kJ -5.006 kJ +61.75 kJ
Multiple Choice Options
- A _ 61.75 kJ mol _ 1
- B + 5.006 kJ mol _ 1
- C _ 5.006 kJ mol _ 1
- D + 61.75 kJ mol _ 1
Step-by-Step Verified Solution
To find the standard Gibbs energy change for the reaction, we can use the relationship between the standard Gibbs free energy change ( _ G _ ) and the standard cell potential ( E _ ) given by the following equation:
_ G _ = _ n F E _
Where:
n is the number of moles of electrons transferred in the reaction.
F is the Faraday constant ( 1 F = 96487 C _ mol _ 1 ).
E _ is the standard cell potential.
From the given reaction:
Zn ( s ) + Fe 2 + ( aq ) _ Zn 2 + ( aq ) + Fe ( s )
It can be observed that n = 2 because two electrons are transferred from zinc to iron.
Given data:
E _ = 0.32 V
1 F = 96487 C / mol
Now, substitute the values into the equation:
_ G _ = _ n F E _
_ G _ = _ 2 _ 96487 C / mol _ 0.32 V
Calculate the value:
_ G _ = _ 2 _ 96487 C / mol _ 0.32 V
_ G _ = _ 2 _ 30875.84 J / mol
_ G _ = _ 61751.68 J / mol
Converting the units to kJ/mol:
_ G _ = _ 61.75168 kJ / mol
The closest answer, when rounded to two decimal places, is:
_ G _ = _ 61.75 kJ / mol
Therefore, the correct option is:
Option A: _ 61.75 kJ mol _ 1