Verified Solution • 2025–26 Session moderate

QNEET-2024-Ch-109: NEET 2024 Chemistry - Class 12 NEET-2024-Ch-109 Solution: The standard cell potential of the following cell \(Zn

The standard cell potential of the following cell Zn∣Zn2+(aq)∣∣Fe2+(aq)∣FeZn | Zn^{2+}(aq) || Fe^{2+}(aq) | Fe is 0.32 V. Calculate the standard Gibbs energy change for the reaction: Zn(s)+Fe2+(aq)→Zn2+(aq)+Fe(s)Zn(s) + Fe^{2+}(aq) \rightarrow Zn^{2+}(aq) + Fe(s) (Given: 1F=96487 C1 F = 96487\ \text{C}) -61.75 kJ mol−1mol^{-1} +5.006 kJ mol−1mol^{-1} -5.006 kJ mol−1mol^{-1} +61.75 kJ mol−1mol^{-1}

Multiple Choice Options

  • A −61.75 kJ mol−1-61.75 \mathrm{~kJ} \mathrm{~mol}^{-1} _ 61.75   kJ   mol _ 1
  • B +5.006 kJ mol−1+5.006 \mathrm{~kJ} \mathrm{~mol}^{-1} + 5.006   kJ   mol _ 1
  • C −5.006 kJ mol−1-5.006 \mathrm{~kJ} \mathrm{~mol}^{-1} _ 5.006   kJ   mol _ 1
  • D +61.75 kJ mol−1+61.75 \mathrm{~kJ} \mathrm{~mol}^{-1} + 61.75   kJ   mol _ 1

Step-by-Step Verified Solution

To find the standard Gibbs energy change for the reaction, we can use the relationship between the standard Gibbs free energy change ( _ G _ ) and the standard cell potential ( E _ ) given by the following equation: _ G _ = _ n F E _ Where: n is the number of moles of electrons transferred in the reaction. F is the Faraday constant ( 1   F = 96487   C _ mol _ 1 ). E _ is the standard cell potential. From the given reaction: Zn ( s ) + Fe 2 + ( aq ) _ Zn 2 + ( aq ) + Fe ( s ) It can be observed that n = 2 because two electrons are transferred from zinc to iron. Given data: E _ = 0.32   V 1   F = 96487 C / mol Now, substitute the values into the equation: _ G _ = _ n F E _ _ G _ = _ 2 _ 96487   C / mol _ 0.32   V Calculate the value: _ G _ = _ 2 _ 96487   C / mol _ 0.32   V _ G _ = _ 2 _ 30875.84   J / mol _ G _ = _ 61751.68   J / mol Converting the units to kJ/mol: _ G _ = _ 61.75168   kJ / mol The closest answer, when rounded to two decimal places, is: _ G _ = _ 61.75   kJ / mol Therefore, the correct option is: Option A: _ 61.75   kJ   mol _ 1

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