Verified Solution • 2025–26 Session moderate

QNEET-2024-Ch-1: NEET 2024 Chemistry - Class 11 NEET-2024-Ch-1 Solution: For the reaction \(2A B + C\) \(K_c = 4 10^{-3}\). At a given…

For the reaction 2A⇌B+C2A \rightleftharpoons B + C Kc=4×10−3K_c = 4 \times 10^{-3}. At a given time the composition of reaction mixture is: [A]=[B]=[C]=2×10−3 M[A] = [B] = [C] = 2 \times 10^{-3}\ \text{M}. Then which of the following is correct?

Multiple Choice Options

  • A Reaction is at equilibrium.
  • B Reaction has a tendency to go in forward direction.
  • C Reaction has a tendency to go in backward direction.
  • D Reaction has gone to completion in forward direction.

Step-by-Step Verified Solution

Step-by-Step Calculation

  1. Calculate the reaction quotient (QcQ_c): For the balanced equilibrium:
  2. 2A⇌B+C2\text{A} \rightleftharpoons \text{B} + \text{C}
  3. The expression for the reaction quotient is:
  4. Qc=[B][C][A]2Q_c = \frac{[\text{B}][\text{C}]}{[\text{A}]^2}
  5. Substitute the given concentrations:
  6. Qc=(2×10−3)(2×10−3)(2×10−3)2=4×10−64×10−6=1Q_c = \frac{(2 \times 10^{-3})(2 \times 10^{-3})}{(2 \times 10^{-3})^2} = \frac{4 \times 10^{-6}}{4 \times 10^{-6}} = 1
  7. Compare QcQ_c with KcK_c:
  8. Qc=1Q_c = 1
  9. Kc=4×10−3K_c = 4 \times 10^{-3}
  10. Since Q_c > K_c, the concentration of products is higher than at equilibrium. To achieve equilibrium, the system will shift to the left, consuming products to form reactants.

Therefore, the reaction has a tendency to proceed in the backward direction.

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