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QNEET-2018-Ch-857: NEET 2018 Chemistry - Class 12 NEET-2018-Ch-857 Solution: The geometry and magnetic behaviour of the complex…

The geometry and magnetic behaviour of the complex [Ni(CO)4][Ni(CO)_4] are square planar geometry and diamagnetic tetrahedral geometry and diamagnetic square planar geometry and paramagnetic tetrahedral geometry and paramagnetic.

Multiple Choice Options

  • A square planar geometry and diamagnetic
  • B tetrahedral geometry and diamagnetic
  • C square planar geometry and paramagnetic
  • D tetrahedral geometry and paramagnetic.

Step-by-Step Verified Solution

Ni(28) : [Ar]3d 8 4s 2 CO is a strong field ligand, so unpaired electrons get paired. Hence, configuration would be: For, four �CO�-ligands hybridisation would be sp3 and thus the complex would be diamagnetic and of tetrahedral geometry.

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