Verified Solution • 2025–26 Session
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QNEET-2017-Ch-922: NEET 2017 Chemistry - Class 12 NEET-2017-Ch-922 Solution: In the electrochemical cell:…
In the electrochemical cell: the emf of this Daniell cell is . When the concentration of is changed to 1.0 M and that of changed to 0.01 M the emf changes to . From the followings which one is the relationship between and ? (Given RT/F = 0.059)
Multiple Choice Options
- A E 1 < E 2
- B E 1 > E 2
- C E 2 = 0 1 E 1
- D E 1 = E 2
Step-by-Step Verified Solution
E cell = E o - 0.059 n log _ [ Z n 2 + ] [ C u 2 + ]
E 1 = E o - 0.059 2 log _ 0.01 1
= E o - 0.059 2 ( _ 2 ) log _ 10
E 1 = E o + 0.059
E 2 = E o - 0.059 2 log _ 1 0.01
_ E 2 = E o - 0.059 2 log _ 100
_ E 2 = E o - 0.059
_ E 1 > E 2