Verified Solution • 2025–26 Session moderate

QNEET-2013-Ch-1566: NEET 2013 Chemistry - Class 12 NEET-2013-Ch-1566 Solution: On hydrolysis of a 'compound' two compounds are obtained. One…

On hydrolysis of a 'compound' two compounds are obtained. One of which on treatment with sodium nitrite and hydrochloric acid gives a product which does not respond to iodoform test. The second one reduces Tollens reagent and Fehling's solution. The 'compound' is CH3CH2CH2NCCH_3CH_2CH_2NC CH3CH2CH2CNCH_3CH_2CH_2CN CH3CH2CH2ON=OCH_3CH_2CH_2ON=O CH3CH2CH2CON(CH3)2CH_3CH_2CH_2CON(CH_3)_2

Multiple Choice Options

  • A CH 3 CH 2 CH 2 NC
  • B CH 3 CH 2 CH 2 CN
  • C CH 3 CH 2 CH 2 ON == = O
  • D CH 3 CH 2 CH 2 CON(CH 3 ) 2

Step-by-Step Verified Solution

Hydrolysis of propyl isocyanide (CH 3 CH 2 CH 2 NC) gives CH 3 CH 2 CH 2 NH 2 + HCOOH. On treatment with NaNO 2 and HCl I(CH 3 CH 2 CH 2 NH 2 ) gives CH 3 CH 2 CH 2 OH which does not give iodoform test. II (HCOOH) reduces Tollen�s reagent and Fehling�s solution.

Related Learning Resources & Exam Preparation