Verified Solution • 2025–26 Session moderate

QNEET-2013-Ch-1562: NEET 2013 Chemistry - Class 11 NEET-2013-Ch-1562 Solution: In which of the following ionization processes the bond energy…

In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic. O2→O2+O_2 \rightarrow O_2^+ C2→C2+C_2 \rightarrow C_2^+ NO→NO+NO \rightarrow NO^+ N2→N2+N_2 \rightarrow N_2^+

Multiple Choice Options

  • A O 2 →\to _ O 2 +
  • B C 2 →\to _ C 2 +
  • C NO →\to _ NO +
  • D N 2 →\to _ N 2 +

Step-by-Step Verified Solution

Molecular orbital configuration of O 2 + _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 _ 2 p z 2 � 2 p y 2 � _ 2 p x 1 � _ 2 p y 1 _ Paramagnetic Bond order = 10 _ 5 2 = 2.5 C 2 _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 _ 2 p z 2 � 2 p y 2 _ Diamagnetic Bond order = 8 _ 4 2 = 2 C 2 + _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 _ 2 p z 2 � 2 p y 1 _ Paramagnetic Bond order = 7 _ 4 2 = 1.5 NO _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 _ 2 p z 2 � 2 p y 2 � _ 2 p x 1 _ Paramagnetic Bond order = 10 _ 5 2 = 2.5 NO + _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 _ 2 p z 2 � 2 p x 2 � 2 p y 2 _ Diamagnetic Bond order = 10 _ 4 2 = 3 N 2 _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 � 2 p x 2 � 2 p y 2 _ 2 p z 2 _ Paramagnetic Bond order = 10 _ 4 2 = 3 N 2 + _ _ 1 s 2 _ _ 1 s 2 _ 2 s 2 _ _ 2 s 2 � 2 p x 2 � 2 p y 2 _ 2 p z 1 _ Paramagnetic Bond order = 9 _ 4 2 = 2.5

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