Verified Solution • 2025–26 Session moderate

QNEET-2013-Ch-1476: NEET 2013 Chemistry - Class 11 NEET-2013-Ch-1476 Solution: \(KMnO_4\) can be prepared from \(K_2MnO_4\) as per the…

KMnO4KMnO_4 can be prepared from K2MnO4K_2MnO_4 as per the reaction 3MnO42−+2H2O⇌2MnO4−+MnO2+4OH−3MnO_4^{2-} + 2H_2O \rightleftharpoons 2MnO_4^- + MnO_2 + 4OH^- The reaction can go to completion by removing OH−OH^- ions by adding CO2CO_2 SO2SO_2 HCl KOH

Multiple Choice Options

  • A CO 2
  • B SO 2
  • C HCl
  • D KOH

Step-by-Step Verified Solution

KOH is the base thus, it gives OH � ions thus it cannot remove OH � ions from reaction mixture but it adds on the concentration of OH � ions. So, an acid must be added but if a strong acid is added to the reaction mixture then in acidic condition the MnO 4 � formed reduces to give Mn 2+ thus, HCl which is a strong acid and SO 2 which on treating with water forms a strong H 2 SO 4 cannot be used for this purpose. Thus, CO 2 which forms H 2 CO 3 a weak acid reacts to remove OH � but not that much acidic that MnO 4 � undergo reduction. Thus, CO 2 is used for this reaction for completion.

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