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QAIPM-2012-Ch-1629: NEET 2012 Chemistry - Class 12 AIPM-2012-Ch-1629 Solution: The Gibb's energy for the decomposition of \(Al_2O_3\) at…
The Gibb's energy for the decomposition of at is as follows The potential difference needed for the electrolytic reduction of aluminium oxide () at is at least 4.5 V 3.0 V 2.5 V 5.0 V
Multiple Choice Options
- A 4.5 V
- B 3.0 V
- C 2.5 V
- D 5.0 V
Step-by-Step Verified Solution
We know,
_ G o = � nFE o
2 3 Al 2 O 3 _ 4 3 Al + O 2
Total number of Al atoms in Al 2 O 3
= 2 3 _ 2 = 4 3
Al 3+ + 3e � _ Al
As 3e � change occur for each Al atom
_ n = 4 3 _ 3 = 4
E o = - _ G _ n F
= - 960 _ 1000 4 _ 96500
= - 2.5 V