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QAIPM-2011-Ch-1846: NEET 2011 Chemistry - Class 12 AIPM-2011-Ch-1846 Solution: The Lassaigne's extract is boiled with conc. \(HNO_3\) while…
The Lassaigne's extract is boiled with conc. while testing for halogens. By doing so it
Multiple Choice Options
- A decomposes and NaCN, formed
- B helps in the precipitation of AgCl
- C increases the solubility product of AgCl
- D increases the concentration of ions
Step-by-Step Verified Solution
In case of Lassaigne�s test of halogens, it is
necessary to remove NaCN and Na 2 S from the
sodium extract, if nitrogen and sulphur are present.
This is done by boiling the sodium extract with
conc. HNO 3 .
NaCN + HNO 3 _ NaNO 3
+ HCN _
Na 2 S + 2HNO 3 _ 2NaNO 3
+ H 2 S _