Verified Solution • 2025–26 Session moderate

QAIPMT-2010-Ch-2036: NEET 2010 Chemistry - Class 12 AIPMT-2010-Ch-2036 Solution: Given are cyclohexanol (I), acetic acid (II), 2, 4,…

Given are cyclohexanol (I), acetic acid (II), 2, 4, 6-trinitrophenol (III) and phenol (IV). In these the order of decreasing acidic character will be

Multiple Choice Options

  • A III>II>IV>IIII>II>IV>I
  • B II>III>I>IVII>III>I>IV
  • C II>III>IV>III>III>IV>I
  • D III>IV>II>IIII>IV>II>I

Step-by-Step Verified Solution

As we know that phenols and carboxylic acids are more acidic than aliphatic alcohols thus cyclohexanol is least acidic. On the other hand III is more acidic than IV because of the presence of three highly electron with drawing NO 2 groups on the benzene ring which makes the OH bond extremely polarized. This facilitates the release of H + . In acetic acid the electron withdrawing _ C | = O group polarizes the O-H bond and increases the acid strength. Thus, acetic acid is more acidic than phenol or cyclohexanol. Thus, the order of acidic strength will be III > II > IV > I

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