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QAIPMT-2010-Ch-2020: NEET 2010 Chemistry - Class 11 AIPMT-2010-Ch-2020 Solution: In which one of the following species the central atom has the…

In which one of the following species the central atom has the type of hybridization which is not the same as that present in the other three?

Multiple Choice Options

  • A SF4SF_4
  • B I3−I_3^-
  • C SbCl52−SbCl_5^{2-}
  • D PCl5PCl_5

Step-by-Step Verified Solution

The hybridisation of the central atom can be calculated as H = 1 2 [ ( N o . o f e l e c t r o n s i n v a l e n c e s h e l l o f a t o m ) + ( N o . o f m o n o v a l e n t a t o m s a r o u n d c e n t r a l a t o m ) _ ( C h arge o n c a t i o n ) + ( C h arge o n a n i o n ) ] Applying that formula we find that all the given species except [SbCl 5 ] 2- have central atom with sp 3 d ( corresponding to H = 5) hybridisation. In [SbCl 5 ] 2- Sb is sp 3 d 2 hybridized.

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