Verified Solution • 2025–26 Session moderate

QAIPMT-2010-Ch-2014: NEET 2010 Chemistry - Class 12 AIPMT-2010-Ch-2014 Solution: Among the following four compounds (i) Phenol (ii) Methyl…

Among the following four compounds (i) Phenol (ii) Methyl phenol (iii) Meta-nitrophenol (iv) Para-nitrophenol. The acidity order is

Multiple Choice Options

  • A (iv)>(iii)>(i)>(ii)(iv)>(iii)>(i)>(ii)
  • B (iii)>(iv)>(i)>(ii)(iii)>(iv)>(i)>(ii)
  • C (i)>(iv)>(iii)>(ii)(i)>(iv)>(iii)>(ii)
  • D (ii)>(i)>(iii)>(iv)(ii)>(i)>(iii)>(iv)

Step-by-Step Verified Solution

In phenols, the presence of electron releasing groups decrease the acidity, whereas presence of electron withdrawing groups increase the acidity, compared to phenol. Among the meta and para-nitrophenols, the latter is more acidic as the presence of �NO 2 group at para position stabilises the phenoxide ion to a greater extent than when it is present at meta position. Thus, correct order of acidity is : (iv) > (iii) > (i) > (ii)

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