Verified Solution • 2025–26 Session moderate

QAIPMT-2009-Ch-2111: NEET 2009 Chemistry - Class 12 AIPMT-2009-Ch-2111 Solution: A 0.0020 m aqueous solution of an ionic compound…

A 0.0020 m aqueous solution of an ionic compound [Co(NH3)5(NO2)]Cl[Co(NH_3)_5(NO_2)]Cl freezes at −0.00732∘C-0.00732^\circ C. Number of moles of ions which 1 mol of ionic compound produces on being dissolved in water will be (Kf=1.86∘C/mK_f = 1.86^\circ C/m) 3 4 1 2

Multiple Choice Options

  • A 0.90 V
  • B 0.30 V
  • C 0.38 V
  • D 0.52 V

Step-by-Step Verified Solution

For the reaction, Cu 2+ + 2e _ _ Cu,  E o = 0.337 V _ G o = - nFE o = � 2 _ F _ 0.337 = � 0.674 F ......(i) For the reaction, Cu 2+ + e _ _ Cu + ,  E o = 0.153 V _ G o = - nFE o = � 1 _ F _ � 0.153 = 0.153 F On adding eqn (i) & (ii) Cu 2+ + e _ _ Cu + _ G o = �0.521 F = �nFE� _ E� = 0.52 V

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