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QAIPMT-2008-Ch-2199: NEET 2008 Chemistry - Class 11 AIPMT-2008-Ch-2199 Solution: Four diatomic species are listed below. Identify the correct…
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them
Multiple Choice Options
- A 36:01:00
- B 1:01
- C 3:01
- D 1:09
Step-by-Step Verified Solution
Given
X _ Y + Z . . . .(i)
A _ 2B . . . .(ii)
Let the total pressure for reaction (i) and (ii) be
P 1 and P 2 respectively, then
K P 1 K P 2 = 9 1
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X | _ | Y | + | Z
Initial mole | 1 | 0 | 0
At equilibrium | 1 - _ | _ | _
Total number of moles at equilibrium
= 1 - _ + _ + _ = 1 + _
_ K P 1 = P Y _ P Z P X = _ 1 + _ _ P 1 _ _ 1 + _ _ P 1 1 _ _ 1 + _ _ P 1
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A | _ | 2B
Initial mole | 1 | 0
At equilibrium | 1 - _ | 2 _
Total number of moles at equilibrium
= 1 - _ + 2 _ = 1 + _
_ K P 2 = ( P B ) 2 P A = ( 2 _ 1 + _ _ P 2 ) 2 1 _ _ 1 + _ _ P 2
_ K P 1 K P 2 = P 1 4 P 2
_ P 1 4 P 2 = 9 1
_ P 1 P 2 = 36 1