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QAIPMT-2006-Ch-2415: NEET 2006 Chemistry - Class 12 AIPMT-2006-Ch-2415 Solution: \([Cr(H_2O)_6]Cl_3\) (At. no. of Cr = 24) has a magnetic moment …
(At. no. of Cr = 24) has a magnetic moment of 3.83 B.M. The correct distribution of 3d electrons in the chromium of the complex is
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Step-by-Step Verified Solution
3.83 = n ( n + 2 )
_ n = 3
Thus, number of unpaired electrons in d-orbitals subshells of chromium (Cr = 24) = 3
_ Configuration of Cr = 1s 2 2s 2 2p 6 3s 2 3p 6 3d 3
In 3d 3 the distribution of electrons
3 d x y 1 , 3 d y z 1 , 3 d x z 1 , 3 d x 2 _ y 2 0 , 3 d z 2 0