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QAIPMT-2006-Ch-2389: NEET 2006 Chemistry - Class 12 AIPMT-2006-Ch-2389 Solution: Identify the correct statement for change of Gibbs energy for a …
Identify the correct statement for change of Gibbs energy for a system () at constant temperature and pressure:
Multiple Choice Options
- A - **(A)** If , the process is not spontaneous.
- B - **(B)** If , the process is spontaneous.
- C - **(C)** If , the system has attained equilibrium.
- D - **(D)** If , the system is still moving in a particular direction.
Step-by-Step Verified Solution
Step-by-Step Thermodynamics Explanation
Gibbs Free Energy change () acts as a definitive thermodynamic indicator for the spontaneity of a chemical reaction or physical process taking place at constant temperature and pressure.
The core rules governing are:
1. (Negative Value):
� The process is spontaneous in the forward direction. It can occur naturally without needing external work to drive it.
2. (Positive Value):
� The process is non-spontaneous in the forward direction. It requires a continuous input of energy to proceed. (The reverse process, however, would be spontaneous).
3. (Zero):
� The system has attained dynamic chemical equilibrium. The rates of the forward and backward reactions are perfectly balanced, and there is no net driving force pushing the system in a particular direction.