Verified Solution • 2025–26 Session moderate

QAIPMT-2006-Ch-2389: NEET 2006 Chemistry - Class 12 AIPMT-2006-Ch-2389 Solution: Identify the correct statement for change of Gibbs energy for a …

Identify the correct statement for change of Gibbs energy for a system (ΔGsystem\Delta G_{\text{system}}) at constant temperature and pressure:

Multiple Choice Options

  • A - **(A)** If ΔGsystem<0\Delta G_{\text{system}} < 0, the process is not spontaneous.
  • B - **(B)** If ΔGsystem>0\Delta G_{\text{system}} > 0, the process is spontaneous.
  • C - **(C)** If ΔGsystem=0\Delta G_{\text{system}} = 0, the system has attained equilibrium.
  • D - **(D)** If ΔGsystem=0\Delta G_{\text{system}} = 0, the system is still moving in a particular direction.

Step-by-Step Verified Solution

Step-by-Step Thermodynamics Explanation Gibbs Free Energy change (ΔG\Delta G) acts as a definitive thermodynamic indicator for the spontaneity of a chemical reaction or physical process taking place at constant temperature and pressure. The core rules governing ΔGsystem\Delta G_{\text{system}} are: 1. ΔGsystem<0\Delta G_{\text{system}} < 0 (Negative Value): � The process is spontaneous in the forward direction. It can occur naturally without needing external work to drive it. 2. ΔGsystem>0\Delta G_{\text{system}} > 0 (Positive Value): � The process is non-spontaneous in the forward direction. It requires a continuous input of energy to proceed. (The reverse process, however, would be spontaneous). 3. ΔGsystem=0\Delta G_{\text{system}} = 0 (Zero): � The system has attained dynamic chemical equilibrium. The rates of the forward and backward reactions are perfectly balanced, and there is no net driving force pushing the system in a particular direction.

Related Learning Resources & Exam Preparation