Verified Solution • 2025–26 Session moderate

QAIPMT-2006-Ch-2384: NEET 2006 Chemistry - Class 11 AIPMT-2006-Ch-2384 Solution: The electronegativity difference between N and F is greater…

The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3NH_3 (1.5D) is larger than that of NF3NF_3 (0.2 D). This is because

Multiple Choice Options

  • A in NH3NH_3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3NF_3 these are in the same direction
  • B in NH3NH_3 as well as in NF3NF_3 the atomic dipole and bond dipole are in the same direction
  • C in NH3NH_3 the atomic dipole and bond dipole are in the same direction whereas in NF3NF_3 these are in opposite directions
  • D in NH3NH_3 as well as in NF3NF_3 the atomic dipole and bond dipole are in opposite directions.

Step-by-Step Verified Solution

The dipole moment of NF 3 is 0.24 D and of NH 3 is 1.48 D. In NF 3 , the dipole moment vector are aligned in opposite direction to that of the dipole moment vector of lone pair on N�atom which partly cancel out. On the other hand, N�H bonds in NH 3 are in the same direction of dipole moment of the lone pair on N-atom which adds up the new resultant dipole moment.

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