Verified Solution • 2025–26 Session moderate

QAIPMT-2006-Ch-2383: NEET 2006 Chemistry - Class 11 AIPMT-2006-Ch-2383 Solution: The enthalpy and entropy change for the reaction: \(Br_2(l) +…

The enthalpy and entropy change for the reaction: Br2(l)+Cl2(g)→2BrCl(g)Br_2(l) + Cl_2(g) \rightarrow 2BrCl(g) are 30 kJ mol−130\ \text{kJ mol}^{-1} and 105 J K−1 mol−1105\ \text{J K}^{-1}\ \text{mol}^{-1} respectively. The temperature at which the reaction will be in equilibrium is 300 K 285.7 K 273 K 450 K

Multiple Choice Options

  • A in NH 3 the atomic dipole and bond dipole are in the opposite directions whereas in NF 3 these are in the same direction
  • B in NH 3 as well as in NF 3 the atomic dipole and bond dipole are in the same direction
  • C in NH 3 the atomic dipole and bond dipole are in the same direction whereas in NF 3 these are in opposite directions
  • D in NH 3 as well as in NF 3 the atomic dipole and bond dipole are in opposite directions.

Step-by-Step Verified Solution

The dipole moment of NF 3 is 0.24 D and of NH 3 is 1.48 D. In NF 3 , the dipole moment vector are aligned in opposite direction to that of the dipole moment vector of lone pair on N�atom which partly cancel out. On the other hand, N�H bonds in NH 3 are in the same direction of dipole moment of the lone pair on N-atom which adds up the new resultant dipole moment.

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