Verified Solution • 2025–26 Session moderate

QAIPMT-2006-Ch-2382: NEET 2006 Chemistry - Class 12 AIPMT-2006-Ch-2382 Solution: The electronegativity difference between N and F is greater…

The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3NH_3 (1.5D) is larger than that of NF3NF_3 (0.2 D). This is because in NH3NH_3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3NF_3 these are in the same direction in NH3NH_3 as well as in NF3NF_3 the atomic dipole and bond dipole are in the same direction in NH3NH_3 the atomic dipole and bond dipole are in the same direction whereas in NF3NF_3 these are in opposite directions in NH3NH_3 as well as in NF3NF_3 the atomic dipole and bond dipole are in opposite directions.

Multiple Choice Options

  • A Benzylamine
  • B Diphenylamine
  • C Triphenylamine
  • D pp p -Nitroaniline

Step-by-Step Verified Solution

Benzylamine is more basic than aniline. The reason is that in aniline, the lone pair of nitrogen is conjugated with benzene ring so it is not available readily for others. On the other hand in Benzylamine, nitrogen is not directly attached with ring so lone pairs are not conjugated with ring.

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