Verified Solution • 2025–26 Session moderate

QAIPMT-2003-Ch-2685: NEET 2003 Chemistry - Class 11 AIPMT-2003-Ch-2685 Solution: For which one of the following equations is \( H^ _{react}\)…

For which one of the following equations is ΔHreact∘\Delta H^\circ_{react} equal to ΔHf∘\Delta H^\circ_f for the product?

Multiple Choice Options

  • A Xe(g)+2F2(g)→XeF4(g)Xe(g)+2F_2(g)\rightarrow XeF_4(g)
  • B 2CO(g)+O2(g)→2CO2(g)2CO(g)+O_2(g)\rightarrow 2CO_2(g)
  • C N2(g)+O3(g)→N2O3(g)N_2(g)+O_3(g)\rightarrow N_2O_3(g)
  • D CH4(g)+2Cl2(g)→CH2Cl2(l)+2HCl(g)CH_4(g)+2Cl_2(g)\rightarrow CH_2Cl_2(l)+2HCl(g)

Step-by-Step Verified Solution

Heat of formation, _ H o f of a substance is the amount of heat absorbed or released when one mole of this substance is formed directly from its constituent elements. In option (a), one mole of XeF 4 is formed from its constituent elements i.e., Xe and F 2 thus, the equation has equal value of _ H o r and _ H o f . In option (b), the constituent atoms should be carbon and oxygen only but the reactant used is CO thus, _ H o r � _ H o f In option (c), the reactant used is O 3 which is again not in its element form thus, _ H o r � _ H o f In option (d), two products are formed thus _ H o r � _ H o f

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