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QAIPMT-2003-Ch-2669: NEET 2003 Chemistry - Class 12 AIPMT-2003-Ch-2669 Solution: The e.m.f. of a Daniell cell at 298 K is \(E_1\). When the…
The e.m.f. of a Daniell cell at 298 K is . When the concentration of is 1.0 M and that of is 0.01 M, the e.m.f. changed to . What is the relationship between and ?
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Step-by-Step Verified Solution
Cell reaction is,
Zn + Cu 2+ _ Zn 2+ + Cu
E cell = E o cell - R T n F ln _ [ Z n 2 + ] [ C u 2 + ]
Greater the factor [ Z n 2 + ] [ C u 2 + ] , less is the EMF.
Hence E 1 > E 2