Verified Solution • 2025–26 Session moderate

QAIPMT-2003-Ch-2669: NEET 2003 Chemistry - Class 12 AIPMT-2003-Ch-2669 Solution: The e.m.f. of a Daniell cell at 298 K is \(E_1\). When the…

The e.m.f. of a Daniell cell at 298 K is E1E_1. When the concentration of ZnSO4ZnSO_4 is 1.0 M and that of CuSO4CuSO_4 is 0.01 M, the e.m.f. changed to E2E_2. What is the relationship between E1E_1 and E2E_2?

Multiple Choice Options

  • A E1>E2E_1>E_2
  • B E1<E2E_1<E_2
  • C E1=E2E_1=E_2
  • D E2=0≠E1E_2=0\neq E_1

Step-by-Step Verified Solution

Cell reaction is, Zn + Cu 2+ _ Zn 2+ + Cu E cell = E o cell - R T n F ln _ [ Z n 2 + ] [ C u 2 + ] Greater the factor [ Z n 2 + ] [ C u 2 + ] , less is the EMF. Hence E 1 > E 2

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