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QJEEM25Phecfd: JEE Main 2025 Physics - Class 11 JEEM25Phecfd Solution: An ideal gas initially at temperature, is compressed suddenly…

An ideal gas initially at 0∘C0^{\circ} \mathrm{C} temperature, is compressed suddenly to one fourth of its volume. If the ratio of specific heat at constant pressure to that at constant volume is 3/23 / 2 , the change in temperature due to the thermodynamic process is _________ K.

Step-by-Step Verified Solution

We’re given an ideal gas initially at Ti=0∘C=273 K.T_i = 0^\circ \mathrm{C} = 273\,\mathrm{K}. The gas is suddenly compressed to one-fourth of its initial volume, and we are told that

γ=cpcv=32 .\gamma = \frac{c_p}{c_v} = \frac{3}{2}\,.

For an adiabatic process (one in which there is no heat exchange), if the process were reversible, the relation between the temperature and volume would be

T Vγ−1=constant .T\, V^{\gamma-1} = \text{constant}\,.

Even though the compression is “sudden” (and hence irreversible), the final equilibrium state of the gas is uniquely determined by its internal energy (which is a state function). That allows us to use the adiabatic relation between the initial and final states.

Here are the steps:

Write the adiabatic relation between the initial and final states:

Ti Viγ−1=Tf Vfγ−1 .T_i\, V_i^{\gamma-1} = T_f\, V_f^{\gamma-1}\,.

Since the gas is compressed to one-fourth of its volume, we have

Vf=14Vi .V_f = \frac{1}{4} V_i\,.

Substitute this into the adiabatic relation:

273 Viγ−1=Tf(14Vi)γ−1 .273\,V_i^{\gamma-1} = T_f \left(\frac{1}{4} V_i\right)^{\gamma-1}\,.

With γ=32,\gamma = \frac{3}{2},

γ−1=32−1=12 .\gamma - 1 = \frac{3}{2} - 1 = \frac{1}{2}\,.

So the relation becomes:

273 Vi1/2=Tf(14)1/2Vi1/2 .273\,V_i^{1/2} = T_f \left(\frac{1}{4}\right)^{1/2} V_i^{1/2}\,.

Cancel the common factor Vi1/2V_i^{1/2} (provided it is nonzero) and simplify:

273=Tf(12) .273 = T_f \left(\frac{1}{2}\right)\,.

Now solve for the final temperature TfT_f :

Tf=273×2=546 K .T_f = 273 \times 2 = 546\,\mathrm{K}\,.

The change in temperature is then:

ΔT=Tf−Ti=546−273=273 K .\Delta T = T_f - T_i = 546 - 273 = 273\,\mathrm{K}\,.

So, the change in temperature due to the thermodynamic process is 273 K.\boxed{273\,\mathrm{K}}.

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