Verified Solution • 2025–26 Session moderate

QJEEM25Phb7e9: JEE Main 2025 Physics - Class 11 JEEM25Phb7e9 Solution: Water of mass gram is slowly heated to increase the temperature …

Water of mass mm gram is slowly heated to increase the temperature from T1T_1 to TγT_\gamma . The change in entropy of the water, given specific heat of water is 1Jkg−1 K−11 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1} , is :

Multiple Choice Options

  • A m(T2−T1)\mathrm{m}\left(\mathrm{T}_2-\mathrm{T}_1\right)
  • B zero
  • C mln⁡(T1 T2)\mathrm{m} \ln \left(\frac{\mathrm{T}_1}{\mathrm{~T}_2}\right)
  • D mln⁡(T2 T1)\mathrm{m} \ln \left(\frac{\mathrm{T}_2}{\mathrm{~T}_1}\right)

Step-by-Step Verified Solution

To determine the change in entropy when water is heated from temperature T1T_1 to T2T_2 (here, TγT_\gamma is equivalent to T2T_2 ), we use the definition of entropy change for a reversible process:

ΔS=∫T1T2dQT\Delta S = \int_{T_1}^{T_2} \frac{dQ}{T}

Since the water is being heated slowly, the process is reversible, and the heat added is given by:

dQ=mc dTdQ = mc\,dT

where:

• mm is the mass of the water,

• cc is the specific heat capacity (given as 1 J kg−1 K−11\,\mathrm{J\,kg^{-1}\,K^{-1}} ).

Substitute dQdQ into the integral:

ΔS=∫T1T2mc dTT=mc ∫T1T2dTT.\Delta S = \int_{T_1}^{T_2} \frac{mc\,dT}{T} = mc\, \int_{T_1}^{T_2} \frac{dT}{T}.

Since c=1c = 1 , the equation simplifies to:

ΔS=m∫T1T2dTT.\Delta S = m \int_{T_1}^{T_2} \frac{dT}{T}.

Evaluating the integral, we have:

∫T1T2dTT=ln⁡T∣T1T2=ln⁡(T2T1).\int_{T_1}^{T_2} \frac{dT}{T} = \ln{T}\Big|_{T_1}^{T_2} = \ln\left(\frac{T_2}{T_1}\right).

Thus, the change in entropy is:

ΔS=mln⁡(T2T1).\Delta S = m \ln\left(\frac{T_2}{T_1}\right).

Comparing with the options provided, the correct answer is:

Option D: mln⁡(T2T1).m \ln\left(\frac{T_2}{T_1}\right).

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