Verified Solution • 2025–26 Session moderate

QJEEM25Ph9131: JEE Main 2025 Physics - Class 12 JEEM25Ph9131 Solution: During the transition of electron from state A to state C of a…

During the transition of electron from state A to state C of a Bohr atom, the wavelength of emitted radiation is 2000Ao2000 \mathop A\limits^o and it becomes 6000Ao6000 \mathop A\limits^o when the electron jumps from state B to state C. Then the wavelength of the radiation emitted during the transition of electrons from state A to state B is

Multiple Choice Options

  • A 4000Ao4000 \mathop A\limits^o
  • B 6000Ao6000 \mathop A\limits^o
  • C 2000Ao2000 \mathop A\limits^o
  • D 3000Ao3000 \mathop A\limits^o

Step-by-Step Verified Solution

1λAC=EA−EChc,1λBC=EB−EChc\frac{1}{\lambda_{AC}} = \frac{E_A - E_C}{hc}, \quad \frac{1}{\lambda_{BC}} = \frac{E_B - E_C}{hc}

Since the electron transitions from state A to state C in two steps (A to B and then B to C), the energy difference for the transition from A to B is given by

EA−EB=(EA−EC)−(EB−EC)E_A - E_B = (E_A - E_C) - (E_B - E_C)

Expressing these energy differences in terms of wavelengths,

hcλAB=hcλAC−hcλBC\frac{hc}{\lambda_{AB}} = \frac{hc}{\lambda_{AC}} - \frac{hc}{\lambda_{BC}}

Cancelling out hchc , we obtain

1λAB=1λAC−1λBC\frac{1}{\lambda_{AB}} = \frac{1}{\lambda_{AC}} - \frac{1}{\lambda_{BC}}

Substitute the given values:

1λAB=12000−16000\frac{1}{\lambda_{AB}} = \frac{1}{2000} - \frac{1}{6000}

Finding a common denominator:

1λAB=3−16000=26000=13000\frac{1}{\lambda_{AB}} = \frac{3 - 1}{6000} = \frac{2}{6000} = \frac{1}{3000}

Thus, the wavelength for the A to B transition is

λAB=3000 A˚.\lambda_{AB} = 3000 \, \mathring{A}.

This matches Option D.

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