QJEEM25Cheffe: JEE Main 2025 Chemistry - Class 12 JEEM25Cheffe Solution: Identify correct statements : (A) Primary amines do not give…

Question

Verified Solution • 2025–26 Session moderate

Identify correct statements :

(A) Primary amines do not give diazonium salts when treated with $\mathrm{NaNO}_2$ in acidic condition.

(B) Aliphatic and aromatic primary amines on heating with $\mathrm{CHCl}_3$ and ethanolic KOH form carbylamines.

(C) Secondary and tertiary amines also give carbylamine test.

(D) Benzenesulfonyl chloride is known as Hinsberg's reagent.

(E) Tertiary amines reacts with benzenesulfonyl chloride very easily.

Choose the correct answer from the options given below :

Accepted Answer

(A) $\mathrm{R}-\mathrm{NH}_2 \xrightarrow[\mathrm{HCl}]{\mathrm{NaNO}_2} \mathrm{R}-\mathrm{N}_2^{\oplus} \mathrm{Cl}^{\ominus}$

(B) JEE Main 2025 (Online) 28th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 7 English Explanation 1

(C) Only primary amine gives carbyl amine test

(D) JEE Main 2025 (Online) 28th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 7 English Explanation 2

(E) Tertiary amine do not react with $\mathrm{Ph}-\mathrm{SO}_2 \mathrm{Cl}$

So correct options are (B) and (D) only

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