Verified Solution • 2025–26 Session moderate

QJEEM25Cheb76: JEE Main 2025 Chemistry - Class 12 JEEM25Cheb76 Solution: The standard reduction potential values of some of the p-block…

The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.

Multiple Choice Options

  • A ESn4+/Sn2+o=+1.15 VE^o_{\text{Sn}^{4+}/\text{Sn}^{2+}} = +1.15 \text{ V}
  • B EAl3+/Alo=−1.66 VE^o_{\text{Al}^{3+}/\text{Al}} = -1.66 \text{ V}
  • C EPb4+/Pb2+o=+1.67 VE^o_{\text{Pb}^{4+}/\text{Pb}^{2+}} = +1.67 \text{ V}
  • D ETl3+/Tlo=+1.26 VE^o_{\text{Tl}^{3+}/\text{Tl}} = +1.26 \text{ V}

Step-by-Step Verified Solution

The strength of an oxidizing agent is related to its standard reduction potential. A higher (more positive) standard reduction potential indicates a stronger oxidizing agent because the species is more likely to gain electrons (be reduced).

Given the options:

Option A: ESn4+/Sn2+o=+1.15 VE^o_{\text{Sn}^{4+}/\text{Sn}^{2+}} = +1.15 \text{ V}

Option B: EAl3+/Alo=−1.66 VE^o_{\text{Al}^{3+}/\text{Al}} = -1.66 \text{ V}

Option C: EPb4+/Pb2+o=+1.67 VE^o_{\text{Pb}^{4+}/\text{Pb}^{2+}} = +1.67 \text{ V}

Option D: ETl3+/Tlo=+1.26 VE^o_{\text{Tl}^{3+}/\text{Tl}} = +1.26 \text{ V}

The species with the highest standard reduction potential is the strongest oxidizing agent. In this case, Option C, EPb4+/Pb2+o=+1.67 VE^o_{\text{Pb}^{4+}/\text{Pb}^{2+}} = +1.67 \text{ V} , is the highest value among the given potentials.

Therefore, lead(IV) ion ( Pb4+\text{Pb}^{4+} ) with a reduction potential of +1.67 V+1.67 \text{ V} is the strongest oxidizing agent among the given options.

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