Verified Solution • 2025–26 Session moderate

QJEEM25Chb8fb: JEE Main 2025 Chemistry - Class 12 JEEM25Chb8fb Solution: The reaction follows the mechanism: (fast) (slow) (fast) The…

The reaction A2+B2→2ABA_2 + B_2 \rightarrow 2AB follows the mechanism:

A2⇌k−1k1A+AA_2 \overset{k_1}{\underset{k_{-1}}{\rightleftharpoons}} A + A (fast)

A+B2→k2AB+BA + B_2 \xrightarrow{k_2} AB + B (slow)

A+B→ABA + B \rightarrow AB (fast)

The overall order of the reaction is:

Multiple Choice Options

  • A 0
  • B 1
  • C 2
  • D 3

Step-by-Step Verified Solution

amp;amp; rate =k2[ A][B2].... (1)amp;(k1k−1)=([A]2[ A2])amp;⇒[A]=k1k−1[ A2]amp; Substituting in (1) ; we get amp;amp; Rate =k2k1k−1⋅[ A2]12⋅[ B2]amp;∴ order =(32)=1.5\begin{aligned}&\begin{aligned}& \text { rate }=\mathrm{k}_2[\mathrm{~A}]\left[\mathrm{B}_2\right] \quad\text{.... (1)}\\& \left(\frac{\mathrm{k}_1}{\mathrm{k}_{-1}}\right)=\left(\frac{[\mathrm{A}]^2}{\left[\mathrm{~A}_2\right]}\right) \\& \Rightarrow[\mathrm{A}]=\sqrt{\frac{\mathrm{k}_1}{\mathrm{k}_{-1}}} \sqrt{\left[\mathrm{~A}_2\right]}\end{aligned}\\&\text { Substituting in (1) ; we get }\\&\begin{aligned}& \text { Rate }=\mathrm{k}_2 \sqrt{\frac{\mathrm{k}_1}{\mathrm{k}_{-1}}} \cdot\left[\mathrm{~A}_2\right]^{\frac{1}{2}} \cdot\left[\mathrm{~B}_2\right] \\& \therefore \text { order }=\left(\frac{3}{2}\right)=1.5\end{aligned}\end{aligned}

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