Verified Solution • 2025–26 Session moderate

QJEEM25Ch3062: JEE Main 2025 Chemistry - Class 12 JEEM25Ch3062 Solution: Given below are two statements: Consider the following reaction …

Given below are two statements:

Consider the following reaction

JEE Main 2025 (Online) 23rd January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 7 English 1

Statement (I): In the case of formaldehyde JEE Main 2025 (Online) 23rd January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 7 English 2 is about 2280, due to small substituents, hydration is faster.

Statement (II) : In the case of trichloro acetaldehyde JEE Main 2025 (Online) 23rd January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 7 English 3 is about 2000 due to −- I effect of −- Cl .

In the light of the above statements, choose the correct answer from the options given below :

Multiple Choice Options

  • A Statement I is true but Statement II is false
  • B Both Statement I and Statement II are true
  • C Statement I is false but Statement II is true
  • D Both Statement I and Statement II are false

Step-by-Step Verified Solution

keq=2280\mathrm{k}_{\mathrm{eq}}=2280 is for HCHO

keq=2000\mathrm{k}_{\mathrm{eq}}=2000 is for chloral

Both data is given in clayden and warren book.

\mathrm{k}_{\mathrm{eq}}>1 because HCHO and chloral are more electrophilic.

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