Verified Solution • 2025–26 Session moderate

QJEEM25Ch2b19: JEE Main 2025 Chemistry - Class 11 JEEM25Ch2b19 Solution: The incorrect decreasing order of atomic radii is

The incorrect decreasing order of atomic radii is

Multiple Choice Options

  • A Be>Mg>Al>Si\mathrm{Be}>\mathrm{Mg}>\mathrm{Al}>\mathrm{Si}
  • B Si>P>Cl>F\mathrm{Si}>\mathrm{P}>\mathrm{Cl}>\mathrm{F}
  • C Mg>Al>C>O\mathrm{Mg}>\mathrm{Al}>\mathrm{C}>\mathrm{O}
  • D Al>B>N>F\mathrm{Al}>\mathrm{B}>\mathrm{N}>\mathrm{F}

Step-by-Step Verified Solution

The incorrect order is Be > Mg > Al > Si.

  • Atomic radius increases down a group because the number of electron shells increases. Since Mg\mathrm{Mg} is below Be\mathrm{Be} in Group 2, Mg\mathrm{Mg} must be larger than Be\mathrm{Be} ( \mathrm{Mg} > \mathrm{Be} ).
  • Atomic radius decreases across a period (left to right) due to increasing effective nuclear charge. In Period 3, the order is \mathrm{Mg} > \mathrm{Al} > \mathrm{Si} .

Combining these trends, the correct decreasing order is: \mathrm{Mg} > \mathrm{Al} > \mathrm{Si} > \mathrm{Be}

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