Verified Solution • 2025–26 Session moderate

QJEEM24Phbf47: JEE Main 2024 Physics - Class 11 JEEM24Phbf47 Solution: The pressure and volume of an ideal gas are related as…

The pressure and volume of an ideal gas are related as PV32=K\mathrm{PV}^{\frac{3}{2}}=\mathrm{K} (Constant). The work done when the gas is taken from state A(P1,V1,T1)A\left(P_1, V_1, T_1\right) to state B(P2,V2,T2)B\left(P_2, V_2, T_2\right) is :

Multiple Choice Options

  • A 2(P2V2−P1V1)2\left(\mathrm{P}_2 \sqrt{\mathrm{V}_2}-\mathrm{P}_1 \sqrt{\mathrm{V}_1}\right)
  • B 2(P1 V1−P2 V2)2\left(\sqrt{\mathrm{P}_1} \mathrm{~V}_1-\sqrt{\mathrm{P}_2} \mathrm{~V}_2\right)
  • C 2(P2 V2−P1 V1)2\left(\mathrm{P}_2 \mathrm{~V}_2-\mathrm{P}_1 \mathrm{~V}_1\right)
  • D 2(P1 V1−P2 V2)2\left(\mathrm{P}_1 \mathrm{~V}_1-\mathrm{P}_2 \mathrm{~V}_2\right)

Step-by-Step Verified Solution

To find the work done by the gas when it goes from state A to state B, we can look at the definition of work done on or by a gas in a thermodynamic process. For a quasi-static process, the work done WW is given by the integral of the pressure PP with respect to the volume VV :

W=∫V1V2PdVW = \int_{V_1}^{V_2} P dV

Given the relationship PV32=KPV^{\frac{3}{2}} = K , we can solve for PP :

P=KV32P = \frac{K}{V^{\frac{3}{2}}}

Now, substitute PP into the work integral and evaluate it:

W=∫V1V2KV32dV=K∫V1V2V−32dVW = \int_{V_1}^{V_2} \frac{K}{V^{\frac{3}{2}}} dV = K \int_{V_1}^{V_2} V^{-\frac{3}{2}} dV

To integrate this, we'll use the power rule for integration. The integral of V−32V^{-\frac{3}{2}} is −2V−12-2V^{-\frac{1}{2}} , so the work done is:

W=K[−2V−12]V1V2=K(−2V2−12+2V1−12)W = K \left[-2V^{-\frac{1}{2}}\right]_{V_1}^{V_2} = K \left(-2V_2^{-\frac{1}{2}} + 2V_1^{-\frac{1}{2}} \right)

We can rewrite V−12V^{-\frac{1}{2}} as 1V\frac{1}{\sqrt{V}} :

W=K(−21V2+21V1)W = K \left(-2\frac{1}{\sqrt{V_2}} + 2\frac{1}{\sqrt{V_1}} \right)

Since P2V232=KP_2V_2^{\frac{3}{2}} = K and P1V132=KP_1V_1^{\frac{3}{2}} = K , we can express KK in terms of P1P_1 and V1V_1 (or P2P_2 and V2V_2 , but we’ll use P1P_1 and V1V_1 for now):

W=P1V132(−21V2+21V1)W = P_1V_1^{\frac{3}{2}} \left(-2\frac{1}{\sqrt{V_2}} + 2\frac{1}{\sqrt{V_1}} \right)

W=−2P1V1V11V2+2P1V1V11V1W = -2P_1V_1\sqrt{V_1}\frac{1}{\sqrt{V_2}} + 2P_1V_1\sqrt{V_1}\frac{1}{\sqrt{V_1}}

W=−2P1V1V1V2+2P1V1W = -2P_1V_1\frac{\sqrt{V_1}}{\sqrt{V_2}} + 2P_1V_1

Since V1V2=V1V2\frac{\sqrt{V_1}}{\sqrt{V_2}} = \sqrt{\frac{V_1}{V_2}} , and recalling P2V232=KP_2V_2^{\frac{3}{2}} = K once more:

W=−2P1V1V1V2+2P1V1W = -2P_1V_1\sqrt{\frac{V_1}{V_2}} + 2P_1V_1

W=−2P1V132V2+2P1V1W = -2 \frac{P_1V_1^{\frac{3}{2}}}{\sqrt{V_2}} + 2P_1V_1

Putting P1V132P_1V_1^{\frac{3}{2}} back as KK :

W=−2KV2+2P1V1W = -2\frac{K}{\sqrt{V_2}} + 2P_1V_1

W=−2P2V2V21V2+2P1V1W = -2P_2V_2 \sqrt{V_2}\frac{1}{\sqrt{V_2}} + 2P_1V_1

W=−2P2V2+2P1V1W = -2P_2V_2 + 2P_1V_1

So the work done is:

W=2P1V1−2P2V2W = 2P_1V_1 - 2P_2V_2

Therefore, the correct answer matching the given options is:

Option D: 2(P1 V1−P2 V2)2\left(\mathrm{P}_1 \mathrm{~V}_1-\mathrm{P}_2 \mathrm{~V}_2\right)

Shortcut :


For PVx=\mathrm{PV}^{\mathrm{x}}= constant

If work done by gas is asked then

Wamp;=nRΔT1−xamp; Here x=32∴Wamp;=P2 V2−P1 V1−12=amp;2(P1 V1−P2 V2)\begin{aligned}\mathrm{W} & =\frac{\mathrm{nR} \Delta \mathrm{T}}{1-\mathrm{x}} \\\\& \text { Here } \mathrm{x}=\frac{3}{2} \\\\\therefore \mathrm{W} & =\frac{\mathrm{P}_2 \mathrm{~V}_2-\mathrm{P}_1 \mathrm{~V}_1}{-\frac{1}{2}} \\\\= & 2\left(\mathrm{P}_1 \mathrm{~V}_1-\mathrm{P}_2 \mathrm{~V}_2\right)\end{aligned}

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