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QJEEM24Ph7801: JEE Main 2024 Physics - Class 11 JEEM24Ph7801 Solution: Two moles a monoatomic gas is mixed with six moles of a…

Two moles a monoatomic gas is mixed with six moles of a diatomic gas. The molar specific heat of the mixture at constant volume is :

Multiple Choice Options

  • A 32R\frac{3}{2} \mathrm{R}
  • B 74R\frac{7}{4} \mathrm{R}
  • C 52R\frac{5}{2} \mathrm{R}
  • D 94R\frac{9}{4} \mathrm{R}

Step-by-Step Verified Solution

To calculate the molar specific heat at constant volume of a gas mixture, we can use a weighted average based on the molar specific heats of the individual gases and their respective amounts (moles).

Let's call CV,mC_{V,m} the molar specific heat at constant volume of the mixture, n1n_1 the number of moles of the monoatomic gas, n2n_2 the number of moles of the diatomic gas, CV,m1C_{V,m1} the molar specific heat at constant volume of the monoatomic gas, and CV,m2C_{V,m2} the molar specific heat at constant volume of the diatomic gas.

For a monoatomic ideal gas, the molar specific heat at constant volume is:

CV,m1=32RC_{V,m1} = \frac{3}{2}R

For a diatomic ideal gas, if we assume the gas is rigid and does not exhibit vibrational modes, the molar specific heat at constant volume is:

CV,m2=52RC_{V,m2} = \frac{5}{2}R

The weighted average of the molar specific heat for the mixture is:

CV,m=(n1⋅CV,m1+n2⋅CV,m2)n1+n2C_{V,m} = \frac{(n_1 \cdot C_{V,m1} + n_2 \cdot C_{V,m2})}{n_1 + n_2}

Putting the values into the equation, we get:

CV,m=(2⋅32R+6⋅52R)2+6C_{V,m} = \frac{(2 \cdot \frac{3}{2}R + 6 \cdot \frac{5}{2}R)}{2 + 6}

CV,m=(3R+15R)8C_{V,m} = \frac{(3R + 15R)}{8}

CV,m=18R8C_{V,m} = \frac{18R}{8}

CV,m=94RC_{V,m} = \frac{9}{4}R

Therefore, the molar specific heat of the mixture at constant volume is 94R\frac{9}{4}R . The correct answer is:

Option D

94R\frac{9}{4}R

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