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QJEEM24Cheb55: JEE Main 2024 Chemistry - Class 11 JEEM24Cheb55 Solution: The number of species from the following in which the central…

The number of species from the following in which the central atom uses sp3\mathrm{sp}^3 hybrid orbitals in its bonding is __________.

NH3,SO2,SiO2,BeCl2,CO2,H2O,CH4,BF3\mathrm{NH}_3, \mathrm{SO}_2, \mathrm{SiO}_2, \mathrm{BeCl}_2, \mathrm{CO}_2, \mathrm{H}_2 \mathrm{O}, \mathrm{CH}_4, \mathrm{BF}_3

Step-by-Step Verified Solution

To determine the number of species in which the central atom uses sp3\mathrm{sp}^3 hybrid orbitals in its bonding, we need to analyze the hybridization of each central atom in the given species.

1. NH3\mathrm{NH}_3 (Ammonia):

The central atom is nitrogen. Ammonia has 3 sigma bonds and 1 lone pair. Thus, the steric number is 4, which corresponds to sp3\mathrm{sp}^3 hybridization.

2. SO2\mathrm{SO}_2 (Sulfur dioxide):

The central atom is sulfur. Sulfur dioxide has 2 sigma bonds and 1 lone pair. Thus, the steric number is 3, which corresponds to sp2\mathrm{sp}^2 hybridization.

3. SiO2\mathrm{SiO}_2 (Silicon dioxide):

The central atom is silicon. Silicon dioxide has a linear structure with double bonds, leading to sp\mathrm{sp} hybridization.

4. BeCl2\mathrm{BeCl}_2 (Beryllium chloride):

The central atom is beryllium. Beryllium chloride has 2 sigma bonds and no lone pair. Thus, the steric number is 2, which corresponds to sp\mathrm{sp} hybridization.

5. CO2\mathrm{CO}_2 (Carbon dioxide):

The central atom is carbon. Carbon dioxide has a linear structure with double bonds, leading to sp\mathrm{sp} hybridization.

6. H2O\mathrm{H}_2\mathrm{O} (Water):

The central atom is oxygen. Water has 2 sigma bonds and 2 lone pairs. Thus, the steric number is 4, which corresponds to sp3\mathrm{sp}^3 hybridization.

7. CH4\mathrm{CH}_4 (Methane):

The central atom is carbon. Methane has 4 sigma bonds and no lone pair. Thus, the steric number is 4, which corresponds to sp3\mathrm{sp}^3 hybridization.

8. BF3\mathrm{BF}_3 (Boron trifluoride):

The central atom is boron. Boron trifluoride has 3 sigma bonds and no lone pair. Thus, the steric number is 3, which corresponds to sp2\mathrm{sp}^2 hybridization.

From the above analysis, the species in which the central atom uses sp3\mathrm{sp}^3 hybrid orbitals are:

  • NH3\mathrm{NH}_3
  • H2O\mathrm{H}_2\mathrm{O}
  • CH4\mathrm{CH}_4

Therefore, the number of species where the central atom uses sp3\mathrm{sp}^3 hybrid orbitals is 3.

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