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QJEEM24Chd2b7: JEE Main 2024 Chemistry - Class 12 JEEM24Chd2b7 Solution: The following data were obtained during the first order thermal …

The following data were obtained during the first order thermal decomposition of a gas A at constant volume :

A(g)→2 B( g)+C(g)\mathrm{A}(\mathrm{g}) \rightarrow 2 \mathrm{~B}(\mathrm{~g})+\mathrm{C}(\mathrm{g})

S.No. Time /s Total pressure /(atm)
1. 0 0.1
2. 115 0.28

The rate constant of the reaction is ________ ×10−2 s−1\times 10^{-2} \mathrm{~s}^{-1} (nearest integer)

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JEE Main 2024 (Online) 1st February Evening Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 33 English Explanation
amp;0.1+2x=0.28amp;2x=0.18amp;x=0.09amp; K=1115ln⁡0.10.1−0.09amp;=0.0200sec−1amp;=2×10−2sec−1\begin{aligned} & 0.1+2 \mathrm{x}=0.28 \\\\ & 2 \mathrm{x}=0.18 \\\\ & \mathrm{x}=0.09 \\\\ & \mathrm{~K}=\frac{1}{115} \ln \frac{0.1}{0.1-0.09} \\\\ & =0.0200 \mathrm{sec}^{-1} \\\\ & =2 \times 10^{-2} \mathrm{sec}^{-1}\end{aligned}

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