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QJEEM24Chc938: JEE Main 2024 Chemistry - Class 11 JEEM24Chc938 Solution: For hydrogen atom, energy of an electron in first excited state …

For hydrogen atom, energy of an electron in first excited state is −3.4 eV,K.E-3.4 \mathrm{~eV}, \mathrm{K} . \mathrm{E} . of the same electron of hydrogen atom is x eVx \mathrm{~eV} . Value of xx is _________ ×10−1 eV\times 10^{-1} \mathrm{~eV} . (Nearest integer)

Step-by-Step Verified Solution

To determine the kinetic energy (K.E.) of an electron in the first excited state of a hydrogen atom, we need to understand the relationship between the total energy, potential energy, and kinetic energy in an atom.

In a hydrogen atom, the total energy (E) of an electron in the nth state is given by:

En=−13.6n2 eVE_n = - \frac{13.6}{n^2} \mathrm{~eV}

For the first excited state, n=2n = 2 . So, plugging in the value:

E2=−13.622=−13.64=−3.4 eVE_2 = - \frac{13.6}{2^2} = - \frac{13.6}{4} = - 3.4 \mathrm{~eV}

This value represents the total energy (E) of the electron in the first excited state. According to the virial theorem for an electron in a Coulomb potential (as in a hydrogen atom), the kinetic energy (K.E.) is equal to the negative of the total energy:

K.E.=−E\mathrm{K.E.} = - E

Substituting the total energy we calculated:

K.E.=−(−3.4)=3.4 eV\mathrm{K.E.} = - (-3.4) = 3.4 \mathrm{~eV}

Now, we need to find the value of xx in the form of x×10−1 eVx \times 10^{-1} \mathrm{~eV} .

3.4 eV=34×10−1 eV3.4 \mathrm{~eV} = 34 \times 10^{-1} \mathrm{~eV}

Therefore, the value of xx is 34.

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