QJEEM24Chb8fd: JEE Main 2024 Chemistry - Class 12 JEEM24Chb8fd Solution: Which of the following complex is homoleptic?

A homoleptic complex is one in which a central metal atom or ion is surrounded by only one kind of donor groups, ligands or ions. On the other hand, a heteroleptic complex contains a central metal surrounded by more than one kind of donor groups, ligands or ions.

Let's examine the given options :

Option A: $\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]$

This complex contains two different ligands, ammonia ( $\mathrm{NH}_3$ ) and chloride (Cl). Therefore, it is a heteroleptic complex.

Option B: $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$

Just like Option A, this complex has two types of ligands, ammonia ( $\mathrm{NH}_3$ ) and chloride (Cl), making it a heteroleptic complex.

Option C: $\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$

Again, this complex has ammonia ( $\mathrm{NH}_3$ ) and chloride (Cl) ligands, so it is a heteroleptic complex.

Option D: $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$

This complex has only cyanide (CN) ligands surrounding the nickel ion, with no other types of ligands present. Thus, this is a homoleptic complex because it is coordinated by a single type of ligand.

Therefore, Option D is the correct answer as it represents a homoleptic complex.