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QJEEM24Chb623: JEE Main 2024 Chemistry - Class 11 JEEM24Chb623 Solution: Total number of electrons present in molecular orbitals of and…

Total number of electrons present in (π∗)\left(\pi^*\right) molecular orbitals of O2,O2+\mathrm{O}_2, \mathrm{O}_2^{+} and O2−\mathrm{O}_2^{-} is ________.

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amp;O2(16e):(σ1 s)2(σ1 s∗)2(σ2 s)2(σ2 s∗)2amp;(σ2p)2[(π2p)2=(π2p)2],[(π2p∗)1=(π2p∗)1]\begin{aligned}& \mathrm{O}_2(16 \mathrm{e}):\left(\sigma_{1 \mathrm{~s}}\right)^2\left(\sigma_{1 \mathrm{~s}}^*\right)^2\left(\sigma_{2 \mathrm{~s}}\right)^2\left(\sigma_{2 \mathrm{~s}}^*\right)^2 \\& \left(\sigma_{2 \mathrm{p}}\right)^2\left[\left(\pi_{2 \mathrm{p}}\right)^2=\left(\pi_{2 \mathrm{p}}\right)^2\right],\left[\left(\pi_{2 \mathrm{p}}^*\right)^1=\left(\pi_{2 \mathrm{p}}^*\right)^1\right]\end{aligned}

Number of e−\mathrm{e}^{-} present in (π∗)\left(\pi^*\right) of O2=2\mathrm{O}_2=2

Number of e−\mathrm{e}^{-} present in (π∗)\left(\pi^*\right) of O2+=1\mathrm{O}_2^{+}=1

Number of e−\mathrm{e}^{-} present in (π∗)\left(\pi^*\right) of O2−=3\mathrm{O}_2^{-}=3

So total e−\mathrm{e}^{-} in (π∗)=2+1+3=6\left(\pi^*\right)=2+1+3=6

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