Verified Solution • 2025–26 Session moderate

QJEEM24Chb1bf: JEE Main 2024 Chemistry - Class 12 JEEM24Chb1bf Solution: Given below are two statements : Statement I : Piciric acid is…

Given below are two statements :

Statement I : Piciric acid is 2,4,6 - trinitrotoluene.

Statement II : Phenol - 2,4 - disulphonic acid is treated with Conc. HNO3\mathrm{HNO}_3 to get picric acid.

In the light of the above statements, choose the most appropriate answer from the options given below :

Multiple Choice Options

  • A Statement I is incorrect but Statement II is correct
  • B Both Statement I and Statement II are incorrect
  • C Both Statement I and Statement II are correct
  • D Statement I is correct but Statement II is incorrect

Step-by-Step Verified Solution

Statement I is incorrect, and Statement II is correct.

The correct name for picric acid is 2,4,6-trinitrophenol, not 2,4,6-trinitrotoluene. Meanwhile, phenol-2,4-disulphonic acid, when treated with concentrated nitric acid ( HNO3\mathrm{HNO}_3 ), results in the formation of picric acid.

Thus, the most appropriate option is :

Option A

Statement I is incorrect but Statement II is correct.

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