Verified Solution • 2025–26 Session moderate

QJEEM24Ch24d7: JEE Main 2024 Chemistry - Class 11 JEEM24Ch24d7 Solution: Match List I with List II .tg…

Match List I with List II

LIST I
(Element)
LIST II
(Electronic Configuration)
A. N\mathrm{N} I. [Ar]3 d104 s24p5[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^5
B. S\mathrm{S} II. [Ne]3 s23p4[\mathrm{Ne}] 3 \mathrm{~s}^2 3 \mathrm{p}^4
C. Br\mathrm{Br} III. [He]2 s22p3[\mathrm{He}] 2 \mathrm{~s}^2 2 \mathrm{p}^3
D. Kr\mathrm{Kr} IV. [Ar]3 d104 s24p6[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^6

Choose the correct answer from the options given below:

Multiple Choice Options

  • A A-IV, B-III, C-II, D-I
  • B A-I, B-IV, C-III, D-II
  • C A-III, B-II, C-I, D-IV
  • D A-II, B-I, C-IV, D-III

Step-by-Step Verified Solution

To match each element with its correct electronic configuration, let's consider the electronic configurations of each element based on their positions in the periodic table:

  • Nitrogen (N): It is in the 2nd period and belongs to the p-block, specifically group 15. The electronic configuration of nitrogen is 1s22s22p31\text{s}^2 2\text{s}^2 2\text{p}^3 . Looking at the options in List II, this matches with the electronic configuration labeled 'III' ( [He]2s22p3[\mathrm{He}] 2 \mathrm{s}^2 2 \mathrm{p}^3 ), which reflects the electronic configuration of nitrogen starting after the helium core.

  • Sulfur (S): Sulfur is in the 3rd period, also in the p-block, specifically group 16. Its electronic configuration is 1s22s22p63s23p41\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}^2 3\text{p}^4 . In the given list, this corresponds to 'II' ( [Ne]3s23p4[\mathrm{Ne}] 3 \mathrm{s}^2 3 \mathrm{p}^4 ), which captures the configuration of sulfur starting after the neon core.

  • Bromine (Br): Bromine is located in the 4th period and in the p-block, belonging to group 17. Its electronic configuration is 1s22s22p63s23p63d104s24p51\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}^2 3\text{p}^6 3\text{d}^{10} 4\text{s}^2 4\text{p}^5 , which is correctly represented by 'I' ( [Ar]3d104s24p5[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^5 ), showing the configuration after the argon core.

  • Krypton (Kr): Krypton falls in the 4th period and is a noble gas situated in the p-block at group 18. Its electronic configuration is 1s22s22p63s23p63d104s24p61\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}^2 3\text{p}^6 3\text{d}^{10} 4\text{s}^2 4\text{p}^6 , which aligns with 'IV' ( [Ar]3d104s24p6[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^6 ), clearly depicting krypton's electronic configuration post-argon.

Therefore, the correct match is:

  1. A-III (Nitrogen matches with [He]2s22p3[\mathrm{He}] 2 \mathrm{s}^2 2 \mathrm{p}^3 )
  2. B-II (Sulfur matches with [Ne]3s23p4[\mathrm{Ne}] 3 \mathrm{s}^2 3 \mathrm{p}^4 )
  3. C-I (Bromine matches with [Ar]3d104s24p5[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^5 )
  4. D-IV (Krypton matches with [Ar]3d104s24p6[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^2 4 \mathrm{p}^6 )

Thus, the correct answer is Option C: A-III, B-II, C-I, D-IV.

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