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QJEEM24Ch0694: JEE Main 2024 Chemistry - Class 11 JEEM24Ch0694 Solution: A diatomic molecule has a dipole moment of 1.2   D . If…

A diatomic molecule has a dipole moment of 1.2 D. If the bond distance is 1 A∘, then fractional charge on each atom is _________ ×10−1 esu.

(Given 1 D=10−18 esucm)

Step-by-Step Verified Solution

To find the fractional charge on each atom in a diatomic molecule, we can use the relationship between dipole moment (μ), charge (q), and distance (d):

μ=q×d

Where:

  • μ is the dipole moment.

  • q is the magnitude of the charge on each atom.

  • d is the distance between the charges.

First, convert units to be consistent with esu:

  • Bond distance in cm: 1 A∘=1×10−8 cm

  • Dipole moment in esu·cm: 1.2 D=1.2×10−18 esucm

We are given that the bond distance ( dd ) is 1 A∘1 \mathrm{~A}^{\circ} and that the dipole moment (μ( \mu ) is 1.2 D1.2 \mathrm{~D} . Using these values, we can calculate the charge ( qq ) as follows:

q=μd

Now plug in the given values:

q=1.2×10−18 esucm1×10−8 cm

q=1.2×10−10 esu

q=1.2×10−9×10−1 esu

q=0.000000012×10−1 esu

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