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QJEEM23Phf54c: JEE Main 2023 Physics - Class 12 JEEM23Phf54c Solution: If 917 A o be the lowest wavelength of Lyman series then the…

If 917 Ao be the lowest wavelength of Lyman series then the lowest wavelength of Balmer series will be ___________ Ao.

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The energy difference formula for transitions between energy levels in a hydrogen atom, which is given by

ΔE=−13.6 eV×(1n12−1n22)\Delta E = -13.6 \, \text{eV} \times \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)

where ( n1n_1 ) and ( n2n_2 ) are the initial and final energy levels, respectively. For the Lyman series, the electron transitions to the ground state (( n1n_1 = 1)), and for the Balmer series, the electron transitions to the first excited state (( n1n_1 = 2)).

From the given information, we have the lowest wavelength in the Lyman series, ( λ1=917 A˚\lambda_1 = 917 \, \text{Å} ). Therefore, the energy difference ( ΔE\Delta E ) for the Lyman series is

ΔE=hcλ1\Delta E = \frac{hc}{\lambda_1}

where (h) is Planck's constant and (c) is the speed of light.

Similarly, for the Balmer series, the energy difference ( ΔE\Delta E ) is

ΔE=−13.6 eV×(122−1∞2)=−13.6 eV×14\Delta E = -13.6 \, \text{eV} \times \left(\frac{1}{2^2} - \frac{1}{\infty^2}\right) = -13.6 \, \text{eV} \times \frac{1}{4}

The corresponding wavelength ( λ2\lambda_2 ) is

λ2=hcΔE\lambda_2 = \frac{hc}{\Delta E}

By comparing ( ΔE\Delta E ) for the Lyman and Balmer series, you found that

λ1λ2=ΔE2ΔE1=14\frac{\lambda_1}{\lambda_2} = \frac{\Delta E_2}{\Delta E_1} = \frac{1}{4}

Therefore, the lowest wavelength in the Balmer series is

λ2=4λ1=4×917 A˚=3668 A˚\lambda_2 = 4 \lambda_1 = 4 \times 917 \, \text{Å} = 3668 \, \text{Å}

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