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QJEEM23Ph5a20: JEE Main 2023 Physics - Class 12 JEEM23Ph5a20 Solution: The de Broglie wavelength of a molecule in a gas at room…

The de Broglie wavelength of a molecule in a gas at room temperature (300 K) is λ1\lambda_1 . If the temperature of the gas is increased to 600 K, then the de Broglie wavelength of the same gas molecule becomes

Multiple Choice Options

  • A 2 λ1\lambda_1
  • B 12\frac{1}{2} λ1\lambda_1
  • C 12\frac{1}{\sqrt2} λ1\lambda_1
  • D 2 λ1\sqrt2~\lambda_1

Step-by-Step Verified Solution

The de Broglie wavelength of a particle is given by:

λ=hp\lambda = \frac{h}{p}

where h is Planck's constant and p is the momentum of the particle. The momentum of a gas molecule can be related to its kinetic energy (which is related to the temperature of the gas) by:

p=2mKp = \sqrt{2mK}

where m is the mass of the molecule and K is the kinetic energy of the molecule.

At a given temperature T, the average kinetic energy of a molecule in a gas is given by:

K=32kTK = \frac{3}{2} kT

where k is Boltzmann's constant.

Therefore, the de Broglie wavelength of a molecule in a gas is given by:

λ=h2m(3/2)kT=h3mkT\lambda = \frac{h}{\sqrt{2m(3/2)kT}} = \frac{h}{\sqrt{3mkT}}

If the temperature of the gas is increased from T = 300 K to T = 600 K, the new de Broglie wavelength becomes:

λ′=h3mk(2T)=h23mkT=12λ\lambda' = \frac{h}{\sqrt{3mk(2T)}} = \frac{h}{\sqrt{2} \sqrt{3mkT}} = \frac{1}{\sqrt{2}} \lambda

So, the de Broglie wavelength of the gas molecule decreases by a factor of 2\sqrt{2} when the temperature of the gas is doubled.

Therefore, the correct answer is λ′=12λ1\lambda' = \frac{1}{\sqrt{2}} \lambda_1

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