Verified Solution • 2025–26 Session moderate

QJEEM23Chec29: JEE Main 2023 Chemistry - Class 11 JEEM23Chec29 Solution: The sum of oxidation state of the metals in and is ___________.

The sum of oxidation state of the metals in Fe(CO)5,VO2+\mathrm{Fe}(\mathrm{CO})_{5}, \mathrm{VO}^{2+} and WO3\mathrm{WO}_{3} is ___________.

Step-by-Step Verified Solution

To find the sum of the oxidation states of the metals in Fe(CO)5\mathrm{Fe(CO)}_{5} , VO2+\mathrm{VO}^{2+} , and WO3\mathrm{WO}_{3} , we first need to find the oxidation states of the metals in each compound.

  1. Fe(CO)5\mathrm{Fe(CO)}_{5} : The compound CO\mathrm{CO} is a neutral ligand, so it does not contribute to the oxidation state of the metal. Hence, the oxidation state of Fe in Fe(CO)5\mathrm{Fe(CO)}_{5} is 0.


  2. VO2+\mathrm{VO}^{2+} : The compound O\mathrm{O} has an oxidation state of -2, and since the overall charge of the compound is +2, the oxidation state of V must be +4 to balance this out.


  3. WO3\mathrm{WO}_{3} : The compound O\mathrm{O} has an oxidation state of -2, and since there are three oxygen atoms, the total oxidation state contributed by oxygen is -6. To balance this out, the oxidation state of W must be +6.

Therefore, the sum of the oxidation states of the metals in these three compounds is 0+4+6=100 + 4 + 6 = 10 .

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