Verified Solution • 2025–26 Session moderate

QJEEM23Che4b6: JEE Main 2023 Chemistry - Class 12 JEEM23Che4b6 Solution: The mismatched combinations are A. Chlorophyll - Co B. Water…

The mismatched combinations are

A. Chlorophyll - Co

B. Water hardness - EDTA

C. Photography −[Ag(CN)2]−

D. Wilkinson catalyst −[(Ph3P)3RhCl]

E. Chelating ligand - D-Penicillamine

Choose the correct answer from the options given below :

Multiple Choice Options

  • A A and E Only
  • B D and E Only
  • C A and C Only
  • D A, C, and E Only

Step-by-Step Verified Solution

Let's analyze each combination :

A. Chlorophyll - Co : Mismatched. Chlorophyll has a magnesium (Mg) ion at its center, not cobalt (Co).

B. Water hardness - EDTA : Correct match. EDTA (ethylenediaminetetraacetic acid) is used to treat water hardness by chelating metal ions like Ca²⁺ and Mg²⁺.

C. Photography - [Ag(CN)₂]⁻ : Mismatched. Silver halides (AgX, where X = Cl, Br, I) are used in photography, not [Ag(CN)₂]⁻.

D. Wilkinson catalyst - [(Ph₃P)₃RhCl] : Correct match. Wilkinson's catalyst is a homogeneous hydrogenation catalyst with the formula [(Ph₃P)₃RhCl].

E. Chelating ligand - D-Penicillamine : Correct match. D-Penicillamine is a chelating agent that can bind to metal ions through multiple coordination sites.

The mismatched combinations are A and C. So, the correct answer is :

A and C Only.

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